If there is ammonia present then you need to deal with that as a priority, even at a low pH high levels are not good and 5ppm is high.
Does the tank have a working bio filter?
Do you treat the new water for chlorine at all, i.e. use a de-chlorinator (such as prime or safe)?
The temp is too low for discus (though may have been a blessing in disguise), typically you should be aiming for 82f as good temp.
There may be other issues going on, but until the water is right everything else will just complicate things.
As for aging water and pH swing, this is the process where the new water is stored for a short time in a holding barrel where it can be heated and aerated - this will drive off any excess CO2 which allows the pH to stabilise. I'm less concerned about pH swings than most, discus are adapted to changing pH conditions, but being able to pre-heat the change water means they have less stress to deal with.
The likely reason they are laying flat is down to the temperature and poor water. Adding an air stone and slowly raising the temperature (82f) will help. But you will have to change water too as 5ppm of ammonia is toxic - and prehgeat the new water as well as de-chlorinate it.