I'm very interested to hear replies on this topic myself. But besides the PH another area of concern for you might be the increased dissolved gases that cold water retains as opposed to warmer water.
In the four months since I've kept discus I've been doing 60% daily WC straight from by tap; my tap water is PH 6.5, 78F and the water in my tank after 24hrs is 4.7 PH. Now this is a big difference in PH but my fish are doing great, two 'pairs' out of my eleven Discus who clean wood & go through the motions together. The pairs are still juveniles 5"- 6" (total length) but I guess they're practicing for when they are old enough to actually mate. I'm still a beginner in this hobby but I can't imagine my Discus being any more healthy & happy than they are. So I really wonder how this Discus PH sensitivity really works? I haven't tested but I know my water is really 'soft' so is this why they're not affected by such a huge daily PH swing?
Looking forward to seeing the replies in this thread.
Kenny