Discus like lots of water changes with stable water that matches their tank water. Same temperature, same pH, same TDS. It really doesn't matter what the pH is, as long as the water you use to change is the same as the water they're in. I never bother checking pH. As for using R/O waste, that water is high in TDS. Discus can do fine in it as long as it's not excessive, imo. I used R/O for my breeding tanks, and just city water for my display tanks. What is the TDS reading of your R/O waste?