Yes they would make a good pair, but at your very early stage of discus keeping, I would advise you to discourage any breeding at this point. Breeding and raising fry is a really dedicated and time consuming task if it is to be done correctly. I wouldn't want you to get burned out on discus this close to the beginning of your experience with them. You might want to let nature take its course in the main tank or pull the eggs if you ever get any. At least for a couple years until you've really got a better grasp on discus keeping. And please know OP I say this with all do respect, by no means am I belittling your fish keeping husbandry or knowledge, I'm just giving a word of wisdom.
Keeping discus and breeding discus are two very different things.