Hi Kevin,
Welcome to SimplyDiscus!
Looks like a few things here... first off the darkening is most likely because they are pigeon base, or at least the pic you posted looks to be. That means it has black pigment that can show under various conditions. Stress will do it and also dark background. Sounds like you have both there. The substrate is blackish in color and whether you don't see it or not I can guarantee the stingray and Arowana are not making these feel comfortable.. They are 3 lone 2.5" discus in a tank with an active predator Just 3 each 2.5" discus in 150 gal tank with no predators would be stressful.. You really want a group of 6-8 or more 2.5" in a tank that large.. Generally they do best in groups as when young. I would really suggest pulling them out and placing them in their own tank at least until much older...Go with a light back ground and no substrate and I bet you see less stress related pepper provided they are otherwise healthy.
hth,
al