Discus are peaceful fish, but they are also cichlids, which means that there will be a certain level of aggression between individuals in a group. It's similar to the hierarchy of a wolf pack -- each fish has a rank.
The fewer discus you have, the worse the aggression is. This is why it's best to always start with 6 fish. Anything less than that usually leads to problems, especially if you only have 2 or 3 fish. For the aggression to be spread out fairly evenly, 6 fish is best.
In this case, your 3 discus got comfortable in the tank and established themselves as the only discus in the tank. The addition of 3 new fish upset that balance, and now the original fish are trying to establish their dominance over the newcomers.
What has to happen now is that all 6 fish have to establish their place in the pecking order. There will be bickering and fighting until that happens. My suggestion is to pull ALL the fish and put them in QT tanks or buckets, then re-arrange a few decorations or something in the tank, then add them all back at the same time. This usually disorients them and makes them all think they're in a new place. That puts everyone on equal ground, so to speak.
It doesn't always work, but it can. You may also buy a cheap divider and separate the new fish until they are strong and eating well, then try and acclimate them like I described above. Stress from being moved to a new tank, added to stress from being harassed by other discus, could lead to secondary issues with your new discus (like hex).
Keep in mind that if you add a divider, the aggression between the 3 original fish might continue to escalate. I'd try pulling them all, then re-adding them and see if it calms them down and gives everyone an equal chance.
Ryan